5.2 Type of hazard – source of ignition source consideration When considering the ignition source, potential sources of ignition are considered according to the ignition energy and surface temperature: Sparks/energy Ignition of the explosive atmosphere is prevented if the ignition energy of the equipment is lower than the minimum ignition energy of the surrounding substances (see 5.2.1 Groups). Hot surfaces The explosive atmosphere can be prevented from igniting if the surface temperature of the equipment is lower than the ignition temperature of the surrounding gas (see 5.2.2 Temperature classes). The following table provides an overview of the groups, the required ignition energy, and the resulting hazardousness of the substances as well as typical material examples. 5.2.1 Groups for gases and dusts in accordance with the standard Devices for use in Group II (gases) and III (dust) potentially explosive atmospheres are divided into groups (IIA, IIB, IIC, and IIIA, IIIB, IIIC), which indicate the maximum ignition energy of the device. A device may only be used if the maximum ignition energy of the device is lower than the minimum ignition energy of the substance (gas or dust mixture). A device with IIC marking may be used for all gases and a device with IIIC marking may be used for all dusts. Gases are more explosive than dusts: for example, devices with IIB are suitable for IIIC. The division into group II in accordance with A, B, C is particularly important for the types of protection, flameproof enclosure (Ex d) and intrinsic safety (Ex i). For flameproof enclosure, it is based on the experimentally determined limit gap width (MWG), which reduces the transmission of the energy of an explosion inside to the explosive atmosphere surrounding the housing so that it is below the minimum ignition energy of the material. For intrinsic safety, the minimum ignition current ratio is decisive, which results in the maximum ignition energy of the Ex i circuit and which must be below the minimum ignition energy of the respective gases. Group Required ignition energy Danger from substances Examples of substances IIA IIB IIC IIIA IIIB IIIC +++ ++ + +++ ++ + + ++ +++ + ++ +++ Acetone, ethane, ammonia, carbon monoxide. Propane, butane, gasoline, diesel fuel, acetaldehyde Methane, ethylene, ethyl ether, ethyl alcohol, hydrogen sulfide Hydrogen, acetylene, carbon disulfide Combustible flyings, e.g., cotton fibers Non-conductive dust, e.g., flour, wood Conductive dust, e.g., aluminum dust Phoenix Contact 29